Chromium trioxide included in the candidate list of substances of very high. Chromium vi oxide cro 3 is a hexavalent chromium that is majorly used as an oxidizing agent. The california health and welfare agency has established a no signi. Stainless steel is widely used in industrial processes because of its resistance to corrosion. This leaflet tells you about the possible health effects, the preventative measures your. The information contained in this brief is meant to be a summary and isnotintended to be comprehensive or take the place of the osha hexavalent chromium standard. Cool the solution and transfer it quantitatively with distilled water rinses to a 25ml volumetric flask, keeping the total volume about 20 ml. As a result, it was added to californias proposition 65 list of toxic substances pdf in december 2008. Chromium cr is a metallic element belonging to the first transitional series of the periodic table. Chromium is a shiny metal, but materials containing chromium 6 may take on a variety of colors and forms, such as liquids, dusts, mists, or fumes. Chromium vi can be reduced to the more stable chromium iii in the presence of reducing agents e. Workers may be harmed from exposure to hexavalent chromium.
Hexavalent chromium is rarely found in nature and is generally manmade. Safety data sheet northwest missouri state university. If seeking medical attention, provide sds document to physician. Osha hexavalent chromium standards onehalf of the pel or if there is a change, for example to the workplace, work practices, materials or processes involved. Material safety data sheet chromic acid 2 chromium compounds has been shown to be associated with lung cancer and gastrointestinal tract tumors. Chromium is also found in chromic acid cro3, chromium compounds, and chromates. Hexavalent chromium and compounds cas registry numbers. Tin or chromium plated sheet steel is considered a. Air sampling performed to comply with either option must have and accuracy of 25% at the 95% con. Adriana arita, max costa, in handbook of epigenetics, 2011. Chromium vi compounds the hexavalent forms of chromium chromates. Niosh considers all crvi compounds to be occupational carcinogens.
This product may be regulated, have exposure limits or other information identified as the following. In order to comply with the federal occupational safety and health administration standards osha and most state plan osha requirements, this. Certain hexavalent chromium compounds have been demonstrated to be carcinogenic on the basis of epidemiological investigations on workers and experimental studies in animals. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Chromium metal cr is a bluish to steelgray brittle solid, often seen in gray powder form that burns if flame heated. Elemental chromium has a cas registry number of 7440473. Virtually all chromium ore is processed via hexavalent chromium, specifically the salt sodium dichromate. Never give anything by mouth to an unconscious person. Hexavalent chromium workshop integrated risk information. Hexavalent chromium crvi standard the bulletin is a summary prepared by survivair of the hexavalent chromium standard as stated by osha. Addresses compositions containing hexavalent chromium.
Hexavalent chromium may also be present in fumes generated during the production or welding of chrome alloys. It comes in several different forms, including trivalent chromium and hexavalent chromium. Department of health and human services, or designee. High filter background concentrations are observed due to the increased sensitivity. Sheet msds and the label to determine product ingredients and important safety. Workplace exposures to this product below the tlv for chromic oxide could. Hexavalent chromium is harmful to the eyes, skin, and respiratory system.
Industrial exposure to certain forms of hexavalent chromium has been. An effective hexavalent chromium program can prevent respiratory related aliments due to overexposure to hexavalent chromium. Hexavalent chromium crvi is a heavy metal component of stainless steel. Hexavalent chromium an overview sciencedirect topics. Other components considered nonhazardous under osha 1910. Individuals experiencing long term exposure to airborne hexavalent chromium particles have a signiicantly increased risk of developing respiratory cancers. Collection and analysis of hexavalent chromium in ambient air prepared by j. It can be prepared by adding concentrated sulphuric acid in potassium dichromate. The purpose of this hexavalent chromium compliance program is to help ensure that worker exposure levels to hexavalent chromium are accurately assessed, and that workers are not exposed to hexavalent chromium at levels that are above the permissible exposure limit pel of 5 micrograms per cubic meter of air 5 ugm3. Hexavalent chromium can be converted, or reduced, to trivalent chromium but this process will not occur in the opposite direction in physiological systems that is, trivalent chromium cannot oxidize to hexavalent chromium in the human body. The hexavalent chromium compounds are reduced to the trivalent form in the presence of oxidizable. Product contains chromium which is an identified carcinogen.
Trivalent chromium is not specifically listed as a. Rarely occurring naturally, most chromium vi compounds are manufactured products or byproducts. Hexavalent chromium crvi is a known carcinogen when inhaled. Chromium trioxide included in the candidate list of substances of very high concern svhc according to regulation ec no. Compliance guide for the hexavalent chromium standards published in 2006 see. Fume from welding stainless steel or nonferrous chromium alloys. Chromium and certain chromium compounds both in humans and experimental animals.
Chromium vi hexavalent chromium or crvi means chromium with a valence of positive six, in any form and in any compound. Workers in many occupations, for example, workers who handle chromatecontaining products and those who weld, grind, or braze stainless steel. Chromium compounds hazard summary chromium occurs in the environment primarily in two valence states, trivalent chromium cr iii and hexavalent chromium cr vi. Sodium dichromate administered in the drinking water caused cancer of the. Hexavalent chromium is a toxic form of the element chromium. This film typically appears to be gold or brown in color, but in some cases may be optionally specified. Only hexavalent chromium is dis cussed in this document. The following table helps give an indication where hexavalent chromium compounds are found and the types. Consequently, when working to comply with the provisions of the osha chromium vi standard 29 cfr 19101. Potassium chromate is a severe pulmonary, skin, and eye irritant and skin sensitizer.
Health and safety executive chromium and you page 2 of 4 swallowing it, through handling food when you have chromium dust on your hands. Chromium vi, also known as hexavalent chromium, is the second most stable oxidation state of chromium. Chromium 6 in the workplace chromium 6 is a very toxic form of the element chromium cr. No warranty, express or implied, is made and labchem inc. Exposure to hexavalent chromium occurs through breathing, ingestion, and contact with the skin. Hexavalent chromium is on the california governors list of chemicals known to cause cancer or reproductive toxicity. May cause severe and permanent damage to the digestive tract. Hexavalent chromium is a known human carcinogen when inhaled and has been shown to cause. Search results for hexavalent chromium at sigmaaldrich. The synonyms, trade name, chemical formula, and identification numbers of chromium and selected salts are reported in table 41.
Hexavalent chromium crvi is a toxic form of the element chromium. Scales nw, inc hexavalent chromium program scales nw, inc hexavalent chromium program page 1 of 4 42014 purpose the purpose of this safety policy is to establish procedures for the protection of safety and health. Highlights of the new crvi hexavalent chromium standard. Hexavalent chromium cr vi is a well known human carcinogen with exposures occurring in both occupational and environmental settings. Lower detection limits exacerbate the background contamination issue.
However, inhalational exposure to crvi affects only a small portion of the population, mainly by occupational exposures. For more information on operations and the typical hexavalent chromium chemicals use, refer to appendix b, which was extract ed from the osha directive cpl 02 02074. Generally, trivalent chromium is recognized as an essential nutrient and is widely used as a nutritional supplement for humans and animals, while hexavalent chromium is recognized as a human carcinogen. The synonyms, trade name, chemical formula, and identification numbers of chromium and selected salts. Section 1 chemical product and company identification. Occupational exposure to cr vi occurs in chromate manufacturing, chrome plating, ferrochrome production, and stainless steel welding. Director means the director of the national institute for occupational safety and health niosh, u. This material may contain approximately 100 ppm hexavalent chromium.
Chronic exposure to water insoluble hexavalent chromium compounds has been shown to be associated with lung cancer and gastrointestinal tract tumors. This product is a trivalent chromium compound that contains less than 500 ppm 0. Selfprotection of the first aiderensure that medical personnel are aware of the materials involved, take precautions to protect themselves and prevent spread of contamination. Hexavalent chromium and its compounds are on the iarc and ntp lists as posing respiratory and sinus cancer risk. In case of irritation from particulate, immediately. Hexavalent chromium is a form of the metallic element. Monitoring methods for hexavalent chromium include niosh methods 7604 by ion chromatography and 7600 by visible absorption spectrophotometry or osha method id215 noted in the hexavalent chromium standard. Chromium hexavalent compounds, often called hexavalent chromium, exist in several forms known as chromates. Hexavalent chromium crvi compounds are a large group of chemicals with varying properties, uses, and workplace exposures. Chromium metal is often alloyed with other metals or plated on metal and plastic substrates to improve corrosion resistance and provide protective coatings.
Close to a half million welders of stainless steel will be affected by this standard, although chromates can also be present in varied industries involving photographic pigments, dyes, surface coatings, paints, inks, plastics, thermal. Fire conditions may produce small amounts of hexavalent chromium and other oxidation products. Hexavalent chromium factsheet national institute of. The dangers of hexavalent chromium chromium 6 in california. The chromium compounds that are considered carcinogenic are hexavalent chromium compounds. Intertek provides testing for chromiumsix hexavalent cr, hexchrom, and certification and compliance services associated with restricted substances, rohs, elv, weee, and other regulations. Chronic exposure to water insoluble hexavalent chromium compounds has been shown to be associated with lung cancer and gastrointestinal.
Material safety data sheet strontium chromate l203e date. Skin exposure can occur during direct handling of hexavalent chromium containing solutions, coatings, and cements. Material safety data sheet chromium alloyed stainless steel grades. An indication that hexavalent chromium has been lost in this manner is a browncolored pvc filter. This method is intended for use by analysts skilled in the operation of ion chromatographic instrumentation and in the. Intertek provides testing for chromium six hexavalent cr, hexchrom, and certification and compliance services associated with restricted substances, rohs, elv, weee, and other regulations. Intertek laboratories test products, parts and components for trace levels of hexavalent chromium and many other chemical. It oxidizes the ch bonds in the aromatic rings to form benzoic acid from alkyl benzene. Hexavalent chromium compounds are manmade and widely used in many different industries. Repeated or prolonged exposure to hexavalent chromium compounds may cause respiratory irritation, nosebleed, ulceration and perforation of the nasal septum. Description of first aid measures general advice if symptoms persist, call a physician. It is harmful to the skin, eyes, blood, and respiratory system. The respiratory tract is also the major target organ for. Call a physician or poison control center immediately.
Type hexavalent chromium the type within this specification refers to chemical conversion coatings with or without hexavalent chromium as an included ingredient of the chemical. Hot work operation such as welding, torch cutting, etc may potentially generate hexavalent chromium which has been identified as a carcinogen. Exposure may occur from natural or industrial sources of chromium. Chronic exposure to water insoluble hexavalent chromium compounds has been shown to be associated with lung cancer and gastrointestinal tract. First aid measures general advice consult a physician. Show this safety data sheet to the doctor in attendance. Approximately 6,000 tonnes 300,000,000 lb of hexavalent chromium were produced in 1985. Information in this msds is from available published sources and is believed to be accurate. Material safety data sheet chromic acid labchem inc. Hexavalent chromium is a carcinogen and a reproductive toxicant for both males and females. Exposure limits are 8hour twa time weighted average unless designated c ceiling or stel short term exposure limit.